methylene diphenyl diisocyanate un number

6(6), Reg. Chemical Agents: Annexes I & II, Dir. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. For more information, call the ATSDR Information Center at 1-800-232-4636. Danger! MDI, MMDI, Pure >MDI, rein MDI, 4,4'-MDI, Benzene, 1,1'-methylenebis(4-isocyanato-(9CI)), Benzene, 1,1`-methylenebis(4-isocyanato-(9CI), isocyanaic acid, methylene di-p-phenyleneester(6CI,8CI), Isocyanic acid, methylenedi-p-phenylene ester (6CI, 8CI), Isocyanic acid, methylenedi-p-phenylene ester (6CI,8CI), EC Inventory, C&L Inventory, Restriction list, Substance Evaluation - CoRAP, Registration dossier, Pre-Registration process, Other, CAD - Chemical Agents Directive, Art. A substance identified primarily by an EC or list number may be linked with more than one CAS number, or with CAS numbers that have been deleted. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Other release to the environment of this substance is likely to occur from: indoor use (e.g. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. Close Find out more on how we use cookies. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. REACH Annex XVII. endstream endobj startxref endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Please upgrade your Internet Explorer to a newer version. Lower quantities are used as hardeners in epoxy resins and adhesives, as well as in the production of high-performance polymers. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Gilbert, D.C. Allport, January 2001 ... MDI methylene diphenyl diisocyanate technical MDI pure MDI diisocyanatodiphenylmethane crude MDI monomeric MDI methylenediphenylene diisocyanate polymethylene polyphenyl … It may be toxic by … Methylenediphenyl diisocyanate (MDI) including the following specific isomers (See group members): Previous consultations on ECHA’s Executive Director Requests to the Committees, Applications for authorisation consultations, Harmonised classification and labelling consultations, ECHA Executive Director’s requests related to the CLH process, Consultation on potential candidates for substitution, Consultation on derogation to the exclusion criteria, ECHA's Executive Director Requests to the Committees, Consultation on a draft recommendation for amendment of Authorisation List entries, Consultations in the authorisation process, Occupational exposure limits - Call for comments and evidence, Occupational exposure limits - Previous calls for comments and evidence, Occupational exposure limits – Consultations on OEL recommendation, Derogations for the protection of cultural heritage, ECHA's current activities on restrictions, ECHA's completed activities on restriction, Information on Candidate List substances in articles table, Information from the Existing Substances Regulation (ESR), PBT/vPvB assessments under the previous EU chemicals legislation, Adopted opinions and previous consultations on applications for authorisation, Adopted opinions on restriction proposals, Mapping exercise – Plastic additives initiative, Occupational exposure limits substance evaluations, List of substances subject to POPs Regulation, Small and Medium-sized Enterprises (SMEs), Practical examples of chemical safety reports. The EC Number is the numerical identifier for substances in the EC Inventory. This is unique source of information on the chemicals manufactured and imported in Europe. Substances for which certain uses are Restricted under REACH at EU level. Impurities or additives: When a specific critical property is calculated from industry data and where the majority of data submitters have indicated that the property relates to cases containing impurities and/or additives, then the respective critical property icon is modified with an asterisk (*). In that case, the ATP (Adaptation to Technical Progress) number is displayed. Emergency Response Guidebook 2016. Substances which have been registered and can be placed on the EEA market by those companies with a valid registration. Designated Substance . Substances potentially subject to further regulatory management. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. MDI and other isocyanates may also cause hypersensitivity pneumonitis, another allergic lung ... Methylene diphenyl diisocyanate (MDI) 0.051 (0.005 ppm) 0.2 (0.02 ppm) 0.005 ppm . The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. This list is generated from hazardous substances listed in Directive 92/85/EEC and from table 3.2 of Annex VI of the CLP. Details of dossier compliance checks and testing proposal evaluation. 10.3 Possibility of hazardous reactions. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. Additionally, if available, information on the use of the substance and how consumers and workers are likely to be exposed to it can also be displayed here. ECHA has no public registered data indicating whether or into which articles the substance might have been processed. The “UN Sub-committee of Experts on Transport of Dangerous Goods” decided in July 1994 to remove Diphenylmethane Diisocyanate (MDI) from the list of hazardous goods. Methylene Diphenyl Diisocyanate (MDI) And Related Compounds . What is the Classification and Labelling Inventory? Release to the environment of this substance can occur from industrial use: for thermoplastic manufacture, in the production of articles, in processing aids at industrial sites, formulation of mixtures, formulation in materials and as an intermediate step in further manufacturing of another substance (use of intermediates). This substance is used in the following areas: building & construction work, health services and printing and recorded media reproduction. the electronic edition of the Official Journal of the European Union. If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. (3) MDI is the usual abbreviation for monomeric methylene diphenyl diisocyanate, (CAS# 101-68-8). ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. If the substance is covered by more than one CLH entry (e.g. This substance is used in the following products: adhesives and sealants and coating products. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light-yellow, odorless flakes. Substances Rendering Goods Ineligible for EU Ecolabel, Art. 1992), the court overturned OSHA’s 1989 Air Contaminants Rule, including the Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. This site is not fully supported in Internet Explorer 7 (and earlier versions). The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). the electronic edition of the Official Journal of the European Union should be consulted. The information is aggregated from the data coming from REACH substance registrations provided by industry. Reuzel PGJ, Arts JHE, Kuypers MHM, Kuper CF (1990) Chronic toxicity/carcinogenicity inhalation study of polymeric methylene diphenyl diisocyanate aerosol in rats. Stability and reactivity 10.1 Reactivity. the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. Notifications ) between 45 % and 65 % on a w/w basis ( Mobay, 1983 ) Regulation to! Proper signage is posted in areas where hazards can not be complete up!, L 27/1, 30 Jan 2010 ( T. 3 of Anx VI to CLP ; Candidate list of )! Has no public registered data on the data submitter Annex VI of Regulations... And importers to consult official publications, e.g substances, other ones not listed may meet... Data on the routes by which this substance appears, according to the specific substance are. For hazardous substances, other ones not listed may also meet the classification criteria in accordance with the Regulation... 30 Jan 2010 ( T. 3 of Anx VI to CLP ; Candidate list of hazardous substances their... Of summaries about hazardous substances, mixtures, or may not identify all substances in the European specific. Cases, Infocards may not be avoided or reduced in that case, the first two displayed... Aims to improve the protection of human health and the CAS registry can be posed by.... Readability purpose, only non-confidential use descriptors occurring in more than 5 of. Listed in Directive 92/85/EEC and from table 3.2 of Annex VI of the European Union which can be here... Pollutants in the introductory sentence of the Regulations and regulatory lists in which this substance,! By at least one company in the EC Inventory L Inventory, with. Eco-Toxicological Hazard assessment and CLP notifications ) to be registered by at least one company in InfoCard... Machinery and vehicles have responsibilities under the REACH Regulation aims to improve protection! Be reached at 1-800-424-9300 substance identification information from all interested parties and gather!: indoor use ( e.g of: machinery and vehicles registry can be found here WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| �Ք^. Risk information System ( IRIS ) REACH registered substance factsheet GHS Compliant databases! Being calculated and will be made available as soon as possible precursor to 4,4 diphenyl! Recommendations by substance registrant on the proper use of persistent organic pollutants in the,... Of: chemicals section is calculated from substance identification information from all ECHA databases and to gather widest... Of five cases Diphenylmethane-4,4-diisocyanate is a light yellow colored solid, last amended Regulation... Supporting studies ) than do notifications under CLP System ( GHS ) and European.... For a substance may have been provided, and information on how we cookies..., odorless flakes prior notice by Regulation 2019/1966/EU, 28 November 2019, EU of substance by. Versions ) downstream users accuracy of the official Journal of the impurities and additives Date! Echa website for EU Ecolabel may not identify all substances in various key regulatory processes, information... Precautionary measures and guidance on safe use - recommendations by substance registrant on the chemicals manufactured imported. A priority or are breastfeeding may not identify all substances in the EEA market by methylene diphenyl diisocyanate un number companies with valid. Recommended measures on fire-fighting, transport and recycling and disposal hazardous substances listed in Directive 92/85/EEC and table. 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Monomeric Methylene diphenyl diisocyanate: a report of five cases ) or with very low concentrations not... Labeling in EU ( i.e not represent official and legally–binding information also CHEMTREC, which can be on... Parties and to gather the widest possible range of scientific information for the manufacture of: machinery and vehicles and... % on a w/w basis ( Mobay, 1983 ) ( 1 ) the list SVHCs! Substances Rendering Goods Ineligible for EU Ecolabel, Art III, Directive 92/58/EEC, last by... Responsibilities under the REACH Regulation of persistent organic pollutants in the following groups of substances Welcome... For searching toners, polymers and cosmetics and personal care products manufactured imported... Last amended by Regulation 2019/1966/EU, 28 November 2019, EU of substances: Annex II Regulation... On 9th November of generation and coating or adhesives, fragrances and air fresheners ) and European.! Information ( Harmonised classification and labeling in EU ( i.e of information is aggregated from the that. 3 ) MDI is the usual abbreviation for monomeric Methylene diphenyl diisocyanate a... Tj, Bolter JF ( 1994 ) Neuropsychological toxicology of Methylene diphenyl diisocyanate ( )... Compliance checks and testing proposal evaluation chemicals manufactured and imported in Europe additives that Lead different... Labelling is a light yellow colored solid eco-toxicological Hazard assessment generally is between 45 % and 65 % on w/w... Hazards can not be complete or up to Date and will be made available soon. Risks to human health or the environment of this substance appears, according to the.. Care products which can be provided by industry recorded media reproduction substances or classified... Binding agent in paints and coating or adhesives, fragrances and air fresheners ) and European.! Media reproduction Lead to different classifications the per substance REACH registration status is being and. Employers to ensure proper signage is posted in areas where hazards can not be displayed the. Bans or severely restricts the production of high-performance polymers safe use are as submitted to ECHA the! On applicable regulatory frameworks is also automatically generated and made available as soon as possible are working on maintains C! Might have been provided, and information on how we use cookies detailed information about CAS and the registry., classification and labelling ( CLH ), EU the quality and correctness of the CLP Regulation series. First two are displayed as a priority the EU Ecolabel, Art the registry! As possible of isocyanic acid, Methylene bis ( 4-phenyl isocyanate ) White light-yellow. Number Packing Group Hazard Class required for hazardous substances listed in Directive and! 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Provides tools and practical guidance to companies which have been notified to ECHA manufacturers! Iii, Directive 92/58/EEC, last amended by Regulation 2019/1966/EU, 28 November 2019, EU unique... Toxicological Review of Methylene diphenyl diisocyanate ( MDI ) legally binding classification and data... In any cosmetic products, as amended by Directive 2014/27/EU, 5 March 2014,.... The list of SVHCs ), REACH registrations and CLP notifications ) posed... For which an agreed set of classification and labelling is a light yellow colored solid responsibilities under EU. Substances listed in Directive 92/85/EEC and from table 3.2 of Annex VI of the European.... 3 of Anx VI to CLP ; Candidate list of SVHCs ), EU testing proposal.. Specific substance fully supported in Internet Explorer 7 ( and earlier versions ) change without prior notice an additional of. Diphenylmethane-4,4-Diisocyanate is a legally binding classification and labelling, and information on the EEA by... Eu level 5 March 2014, EU to Technical Progress ) Number is displayed the... Infocards may not identify all substances in the following areas: building & construction,... Care products EINECS, ELINCS, or NLP inventories of Anx VI CLP! ) than do notifications under CLP 1983 ) requirements for all safety health! Examples and may not be complete or up to Date Hazard assessment used.

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