Phthalic anhydride is the anhydride of phthalic acid. 1.1 Product identifier. CAS # : 85-44-9 Intermediate for Plastizers, Paints, Dyes and Pigments, Polyester Resins. Purchase 85-44-9 Certified Reference Standards from AccuStandard. 저희는 사용자에 맞게 사이트를 설정하여 사용자가 사이트를보다 원활하게 이용할 수 있도록 쿠키를 사용합니다. PubMed:[Determination of malein anhydride in the presence of phthalic anhydride, alpha-naphthochinon and benzoic acid in the air]. Order Phthalic anhydride as Catalog No. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. However, phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,2), and biodegradation test results may be reflective of biodegradation of phthalic acid which is the hydrolysis product of phthalic anhydride(1,2). to NOM-018-STPS-2015 and NMX-R-019-SFCI-2011 MALEIC ANHYDRIDE Version number: GHS 1.0 Date of compilation: 2017-06-05 Mexico: en No: ALVEG 000523 SDS-05: Page: 2 / 13 Phthalic Anhydride (PA) is used as the major ingredient in the manufacture of plasticizers, unsaturated polyester resin, paint and others. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. 500g; Glass bottle. Revision Date: May 16, 2014. Ensure adequate ventilation. GHS Hazard and Precautionary Statements 20:790. Anhydrides. CAS 85-44-9, pH 2 (6 g/l, H₂O, 20 °C). Phthalic anhydride may be used as a reactant in the preparation of N-substituted phthalimides, poly(isothianaphthene) and methyl (S)-2-phthalimido-4-methylt hiobutanoate. This white solid is an important industrial chemical, especially for the large-scale production of plasticizers for plastics. Availability. Phthalic Anhydride. TCC’s phthalic anhydride is a toxic, white crystalline compound used in the manufacture of phthaleins and other dyes, resins, plasticizers, and insecticides. Phthalic anhydride is used in the preparation of primary amines. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. H317 May cause an allergic skin reaction. Phthalic anhydride (PA) occurs as white solid in various forms or clear molten liquid, with an irritating odour. Refer for medical attention. Phthalic anhydride is converted to phthalic acid in the presence of water. Legal Information Sigma-Aldrich offers a number of Phthalic anhydride products. Fresh air, rest. Chemsrc provides Phthalic anhydride(CAS#:85-44-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. If appropriate, moisten first to prevent dusting. Phthalic anhydride did not bioconcentrate in Gambusia (mosquito fish)(4). Keep warm and quiet. Hazard statement(s ) H302 Harmful if swallowed. Purchase 85-44-9 Certified Reference Standards from AccuStandard. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. This is an organic compound obtained by the transformation of ortoxylene (derived from oil) through the use of catalysts (catalytic oxidation process). CAS No: 116088-82-5; Molecular Weight: 240.71500; Molecular Formula: C 10 H 9 CLO 3 SI; … 85-44-9 Phthalic Anhydride 97 201-607-5 No components need to be disclosed according to the applicable regulations. Products / Product Information / Phthalic Anhydride. Coughing, choking, burning sensation in the nose and throat, as well as headache and dizziness can occur. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). : 85-44-9 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking It is used for the production of plasticizers and for different types of unsaturated polyester resins and alkyds. An estimated BCF of 5 was calculated in fish for phthalic anhydride(SRC), using a log Kow of 1.60(1) and a regression-derived equation(2). This is an organic compound obtained by the transformation of ortoxylene (derived from oil) through the use of catalysts (catalytic oxidation process). Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 6 mg/cu m (1 ppm). Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. We provide Phthalic Anhydride safety data sheets view and download at Echemi.com. P284 [In case of inadequate ventilation] wear respiratory protection. Journal of Allergy and Clinical Immunology. Remove contact lenses, if present and easy to do. John Wiley & Sons, Inc. 2005]. We enable science by offering product choice, services, process excellence and our people make it happen. PubMed:[Poisoning caused by phthalic anhydride, maleic anhydride and phthalates]. H318 Causes serious eye damage. Dry. Avoid formation of dust and aerosols. For industry use only. Remove contaminated clothes. Half-upright position. Air concentrations of 25 mg/m3 (4 ppm) produced signs of mucous membrane irritation. SDS & Certificate of Analysis Phthalic anhydride is a common laboratory chemical, Pthalic anhydride has been shown to be esterified with primary alcohols at room temperature. It reacts with strong oxidants and violently on heating with copper oxide or sodium nitrite, causing explosion hazard. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Phthalic anhydride-containing products’ SDS list “food preservatives” as an identified use (InterAtlas 2016, Koppers 2018). Contact info . Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Phthalic anhydride is a principal commercial form of phthalic acid. Give artificial respiration if not breathing. For precautions see section 2.2. Phthalic Acid, wt 0.2% PHTHALIC ANHYDRIDE Phthalic Anhydride 85-44-9 N/A Technical Name: CAS #: Appearance: Technical Parameters: Min Max The above information has been compiled from what we believe to be credible sources.
For personal protection see section 8. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet. Product Name: Phthalic anhydride Product Code: 115080 Chemical Name: Phthalic anhydride Index No: 607-009-00-4 Safety glasses with side-shields conforming to EN166. It is slightly soluble in hot water, hydrolysing to PA, and is soluble in alcohol and carbon disulphide. Phthalic anhydride is an important chemical intermediate in the plastics industry from which are derived numerous phthalate esters that function as plasticizers in synthetic resins. Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet. Section 3 - Hazards Identification Risk advice to man and the environment Toxic if swallowed. %%EOF
Continue rinsing. Phthalic anhydride was reported to have a 5 day theoretical oxygen demand of 73.46% using 0.5 ppm concentration with a sewage inoculum(4). This colorless solid is an important industrial chemical, especially for the large–scale production of plasticizers for plastics. Do NOT induce vomiting. Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. Phthalic anhydride is the organic compound with the formula:-C6H4(CO)2O. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 (7) The chemical formula for phthalic anhydride is CH O , and it has a molecular weight of 148.12 g/mol. View or download the Phthalic anhydride MSDS (Material Safety Data Sheet) or SDS for 800592 from MilliporeSigma. Stepan Company: PHTHALIC ANHYDRIDE FLAKE. Wash and dry hands. Skin - Remove contaminated clothes. Very toxic in contact with skin. Give one or two glasses of water to drink. P280 Wear protective gloves/protective clothing/eye protection/face protection. Refer for medical attention . Pthalic anhydride plays an important role as an intermdiate in the plastics industry as well as a monomer for synthetic resins. Logistics services are available in the United States. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Product Identification. This use meets the definition of “food additive” in Section 201 of the FFDCA, 21 U.S.C. 115080-Phthalic anhydride Version: 2 Revision date: 20/04/2016 Page 1 of 9 Print date: 20/04/2016 -Continued on next page.-SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY/UNDERTAKING. 74 0 obj
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It is the anhydride of phthalic acid. Phthalic Anhydride SDS details show. Insect Repellents. : 85-44-9 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 116088-82-5) SDS. P272 Contaminated work clothing should not be allowed out of the workplace. Chemical Product and Company Identification Product Name: Phthalic Anhydride Distributed By: HB Chemical 1665 Enterprise Parkway Twinsburg Oh 44087 Phone - 330-920-8023 MSDS Prepared By (w Suppliers Input): HB Chemical Chemical Name / Family: Not available If not breathing give artificial respiration consult a physician. ... 요청한 SDS… Phthalic anhydride was reported to be teratogenic in mice following intraperitoneal injection. Click on "I agree" to accept cookies and be able to visit our website directly, or click on " Settings " to manage your cookies yourself. Avoid breathing dust. Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]: Combustible material: may burn but does not ignite readily. Phthalic anhydride for synthesis. Phthalic anhydride is the anhydride of phthalic acid. Phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(3,4) which suggests that leaching may not be an important fate process(SRC). Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases. Eyes - First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. ;�����(����������!i�m@Z���"��Qm����ҕmR���Bﲍ����b
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Anhydrides. Give plenty of water to drink. Phthalic anhydride for synthesis. (6,8) Phthalic anhydride has an odor threshold of 0.053 parts per million (ppm). Synonyms: 1,3-Isobenzofurandione; 1, 2-benzenedicarboxylic acid anhydride; 1, 3-dioxophthalan. Stepan Company: PHTHALIC ANHYDRIDE MOLTEN. 82 (1), 126-133. H317 May cause an allergic skin reaction. P362+P364 Take off contaminated clothing and wash it before reuse. 1988. To request copies of either please click on the Request Product Information button above and complete the form. Evacuate personnel to safe areas. white crystalline solid with choking odour, Lower flammable limit: 1.7% by volume; Upper flammable limit: 10.5% by volume, 1.19 mPa.s at 132\u00b0C; 1.125 mPa.s at 155\u00b0C, ADR/RID: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, IMDG: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, IATA: PHTHALIC ANHYDRIDE with\nmore than 0.05% of maleic anhydride, Inhalation: LC50 Rat inhalation >210 mg/L/1 hr, Toxicity to fish: EC50; Species: Danio rerio (Zebra danio); Conditions: freshwater; renewal; Concentration: 561000 ug/L (95% confidence limit: 320000 to 1000000 ug/L) for 7 days; Effect: developmental, teratogenic measurements /formulated product, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green algae); Conditions: freshwater; static; Concentration: 41400 ug/L (95% confidence limit: 0 to 109100 ug/L) for 96 hr; Effect: population, biomass /active ingredient, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Exclusion of liability : Information contained in this publication is accurate to the best of the knowledge and the belief of the company. INHALATION: PHTHALIC ANHYDRIDE Remove from exposure, restore breathing. of Chem., London, 1940]. Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. 1988. Skin: Wash off with soap and plenty of water. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, Specific target organ toxicity \u2013 single exposure, Category 3, H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Phthalic anhydride is available in both flake and liquid molten form; Knowledgeable, experienced technical assistance. 1. H315 Causes skin irritation. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Refer for medical attention. Most vapors are heavier than air. Articles of Phthalic anhydride are included as well. Click on "I agree" to accept cookies and be able to visit our website directly, or click on " Settings " to manage your cookies yourself. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. Use: Phthalic anhydride’s primary use is as a chemical intermediate in resins and plastics. Solid irritates skin and eyes, causing coughing and sneezing. sds. Urine was also taken from a control group of 22 persons not occupational exposed to phthalic anhydride. Product Identification. Avoid breathing vapors, mist or gas. Undergoes exothmeric nitration with fuming nitric acid-sulfuric acid and may give mixtures of the potentially explosive phthaloyl nitrates or nitrites or their nitro derivatives [Chem. SysKem Chemie: Using a structure estimation method based on molecular connectivity indices(1), the Koc of phthalic anhydride can be estimated to be 10(SRC). Refer for medical attention. Safety Data Sheet (SDS) Revision / Review Date: 6/12/15 1. Packaging 2.5 kg in poly drum 25, 500 g in glass bottle Other Notes Go to Redi-Dri ™ Product Listing 797995. Mixtures of phthalic anhydride and anhydrous CO2 explode violently if heated [Leaflet No. Avoid dust formation. See Chemical Dangers. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 Phthalic Anhydride. Do NOT induce vomiting. h�bbd``b`�$�� �� $���� ��d1��D\q=@DH[�����AD
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Details of the supplier of the safety data sheet Emergency Telephone Number This colorless solid is an important industrial chemical, especially for the large–scale production of plasticizers for plastics. - Find MSDS or SDS, a COA, data sheets and more information. 82 (1), 126-133. Professional logistics support; Benefits. Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. Phthalic anhydride has a reported BCF of 4,053 in Oedogonium (alga) but did not bioconcentrate in Daphnia (water flea) or Physa (snail)(4). Avoid breathing vapours, mist or gas. %PDF-1.5
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According to a classification scheme(2), this estimated Koc value suggests that phthalic anhydride is expected to have very high mobility in soil. TCC’s phthalic anhydride is a toxic, white crystalline compound used in the manufacture of phthaleins and other dyes, resins, plasticizers, and insecticides. 5, Inst. Phthalic Anhydride. text.skipToContent text.skipToNavigation. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. CAS number: 66-44 9 EC number: 201.607-S Chemical formula: C8H403 Product type: Anhydride of organic aromatic d!carboxylic acid. 99MZzr����,i��92/�-����1#'��'/H��#���0A)�F~Ɇ��n�m9����U}d9-�Ɏ1ub`$��3��~��}_�e�i���u�Q�ia�LJ�7�F؉��ub`\ݤ릞��ɮߎ�I�o��\�a�O�/n��3N�Y�5Y�
Y�%��o��pxQ��l����%�\��O!��?���}�bS������.W��dV�jqI���ɷm|,hVo;�����,nZ�uȆ���X-�->���عzJ�l�*;�*��⢾��I!�cJ��1M�Q��V�~�4��n��-]�'�U����|Y�.��. 1972]. To our knowledge the information is accurate and reliable, however, it is not guaranteed. "Phthalic Acids and Other Benzenepolycarboxylic Acids" Kirk-Othmer Encyclopedia of Chemical Technology. to NOM-018-STPS-2015 and NMX-R-019-SFCI-2011 MALEIC ANHYDRIDE Version number: GHS 1.0 Date of compilation: 2017-06-05 Mexico: en No: ALVEG 000523 SDS-05: Page: 2 / 13 Sweep spilled substance into covered containers. Other reactions with phthalic anhydride yield phenolphthalein, benzoic acid, phthalylsulfathiazole (an intestinal antimicrobial agent), and orthophthalic acid. Theoretical BOD was reported to be 44-78% as a result of incubation of 1-4 ppm with sewage inoculum(5). Half-upright position. sds. Stable under recommended storage conditions. Vapors may travel to source of ignition and flash back. Causes serious eye damage. Avoid contact with skin and eyes. P271 Use only outdoors or in a well-ventilated area. SDS & Certificate of Analysis Phthalic anhydride is a common laboratory chemical, Pthalic anhydride has been shown to be esterified with primary alcohols at room temperature. Chemical Product and Company Identification Product Name: Phthalic Anhydride Distributed By: HB Chemical 1665 Enterprise Parkway Twinsburg Oh 44087 Phone - 330-920-8023 MSDS Prepared By (w Suppliers Input): HB Chemical Chemical Name / Family: Not available First aid: Inhalation - Fresh air, rest. PHTHALIC ANHYDRIDE SOLID (FLAKES) with less than 0.05 % maleic anhydride Revision: 0 Last up date: Issued date: January, 2011 pag.2/ 34 This information only concerns the above mentioned product and does not need to be valid if used with other product(s) or in any process. Phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,5) which suggests that bioconcentration in fish may not be an important fate process(SRC). Ventilation along the floor. Phthalic anhydride is a white (lustrous needles) solid that is slightly soluble in water. Hazard classification & labelling Hazard classification and labelling. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell. Phthalic anhydride is a chemical intermediate that reacts readily and produces a broad range of products that process easily and give a wide range of performance characteristics at a low cost. Refer for medical attention . Phthalic anhydride, present at 100 mg/L, reached 85.2% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(3); it was noted that the phthalic anhydride had been hydrolyzed to phthalic acid(3). Rinse and then wash skin with water and soap. Remove contact lenses, if worn, after initial flushing. It was the first anhydride of a dicarboxylic acid to be used commercially. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. P270 Do not eat, drink or smoke when using this product. Do not discharge to sewer systems. PA(Phthalic Anhydride) Introduction PA is white crystal-like flakes at room temperature and transforms into clear colorless liquid at melting point. ATMOSA - The Phthalic Anhydride Company This website uses cookies - more information on this and your rights as a user can be found in our Data protection declaration . Phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,5) which suggests that bioconcentration in fish may not be an important fate process(SRC). CAS No. No studies regarding reproductive or developmental effects in humans were available. P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2021 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, EXO-7-OXABICYCLO[2.2.1]HEPTANE-2,3-DICARBOXYLIC ANHYDRIDE, 5-Isobenzofuransulfonicacid, 1,3-dihydro-1,3-dioxo-, Acetamide,N-(1,3-dihydro-1,3-dioxo-4-isobenzofuranyl)-, 3a-methyl-5,6-dihydro-4H-isobenzofuran-1,3-dione, Polymer of diethylene glycol, phthalic anhydride, maleic anhydride,isophthalic acid, Neodecanoic acid, oxiranylmethyl ester, polymer with ethenylbenzene, 2-hydroxyethyl 2-propenoate, 1,3-isobenzofurandione and methyl 2-methyl-2-propenoate, 1,3-Isobenzofurandione, 5-(trifluoromethyl)-, Phthalic anhydride 85-44-9 Manufacturer/High quality/Best price/In stock, Tianjin century hengtong import&export co., Ltd, Phthalic anhydride CAS 85-44-9 white crystalline solid with choking odour. EYES (SPLASH): PHTHALIC ANHYDRIDE` Immediately flush eyes with water for 15 minutes. Specific serum antibodies against phthalic anhydride in occupationally exposed subjects. Avoid dust formation. (ERG, 2016). 100% Phthalic Anhydride 85‐44‐9 4. Hold eyelids open for complete irrigation. Phthalic anhydride is a white (lustrous needles) solid that is slightly soluble in water. View information & documentation regarding Phthalic anhydride, including CAS, MSDS & more. We offer the following regional Phthalic anhydride analysis and news coverage to keep you informed of factors and developments affecting prices in the Phthalic anhydride marketplace.. Price reporting PA is widely used as raw material for phthalic plasticizer (DOP DINP, DIDP), unsaturated polyester resin, and dye intermediate. Handle with gloves. Phthalic anhydride is a versatile intermediate in organic chemistry, primarily used in the production of general purpose plasticizers, unsaturated polyesters (UPRs), alkyd resins and polyols (APPs). Phthalic anhydride vapour, fume or dust is a primary irritant. H315 Causes skin irritation. Phthalic anhydride-containing products’ SDS list “food preservatives” as an identified use (InterAtlas 2016, Koppers 2018). Avoid breathing dust. (7) The chemical formula for phthalic anhydride is CH O , and it has a molecular weight of 148.12 g/mol. Wash hands before breaks and at the end of workday. SDS #: 605. Phthalic anhydride is an important chemical intermediate in the plastics industry from which are derived numerous phthalate esters that function as plasticizers in synthetic resins. Irritating to eyes, respiratory system and skin. Then store and dispose of according to local regulations. Phthalic anhydride CAS 85-44-9 SDS including Hazard identification, Composition/information on ingredients, First-aid measures, Fire-fighting measures, Accidental release measures, Handling and storage, Exposure controls/personal protection, Physical and chemical properties etc. Hazard statement(s ) H302 Harmful if swallowed. Evacuate personnel to safe areas. Well closed.Chemical stability: Stable under recommended storage conditions. Gloves must be inspected prior to use. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. & Ind. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride Combustible solidDust explosion possible if in powder or granular form, mixed with air.PHTHALIC ANHYDRIDE reacts exothermically with water. Consult a physician. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Learn more about Phthalic anhydride. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Phthalic anhydride has a reported BCF of 4,053 in Oedogonium (alga) but did not bioconcentrate in Daphnia (water flea) or Physa (snail)(4). 37 0 obj
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At pH 6.8 the half-life of phthtalic anhydride in water was prolonged to 61 seconds. Carefully collect remainder. Contact Persons responsible for the SDS open all close all. Our PA Plant is a manufacturing plant which opened for the first time in the Republic of Korea. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Containers may explode when heated or if contaminated with water. AEROBIC: Based on the available experimental biodegradation test results, phthalic anhydride can be classified as readily biodegradable(1). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/... P403+P233 Store in a well-ventilated place. A4; Not classifiable as a human carcinogen. Using OECD Method 301D (closed bottle test) and a domestic sewage inoculum, phthalic anhydride reached 71% of theoretical BOD after 30 days(1). Show this safety data sheet to the doctor in attendance. 58 0 obj
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Phthalic anhydride is also used as a precursor of anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein, and xanthene dyes. Pthalic anhydride plays an important role as an intermdiate in the plastics industry as well as a monomer for synthetic resins. 500g; Glass bottle. P332+P313 If skin irritation occurs: Get medical advice/attention. Strong oxidizers, water [Note: Converted to phthalic acid in hot water]. Ensure adequate ventilation. Personal protection: chemical protection suit including self-contained breathing apparatus. If breathed in, move person into fresh air. endstream
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ATMOSA - The Phthalic Anhydride Company This website uses cookies - more information on this and your rights as a user can be found in our Data protection declaration . Wear self-contained breathing apparatus for firefighting if necessary. Phthalic anhydride is used in the synthesis of primary amines, the agricultural fungicide phaltan, and thalidomide. Eye protection tested and approved under appropriate government standards such as NIOSH ( US ) SDS! Inhalation - fresh air is formed alcohols, amines, and bases download the phthalic in..., 20 °C ) EN 166 ( EU ) DOP DINP, DIDP ), this suggests... Mass 98.06 g/mol Safety Data Sheet ) or EN 166 ( EU ) [ in of. Publication is accurate to the best of the FFDCA, 21 U.S.C such! Chemical intermediate in the nose and throat, as well as a monomer for synthetic resins and bases workplace... Msds & more if contaminated with water for at least 15 minutes of. M ( 1 ppm ) ( SDS ) is for guidance and is in... 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Inhalation: may be FATAL if INHALED technology development and expansion, we now have the world ’ primary! Is widely used as raw material for phthalic anhydride in the air ] mass 98.06 g/mol Data. 1 ) treatment ( see... on this label ): based on the request information! Triply rinsed ( or equivalent ) and offered for recycling or reconditioning 374 derived from.... Did not bioconcentrate in Gambusia ( mosquito fish ) phthalic anhydride sds 4 ) person into fresh air clothing should be... Flash back contact Persons responsible for the production of plasticizers and for different of...: -C6H4 ( CO ) 2O was reported to be reliable anhydrous CO2 explode violently if heated [ No! Identified use ( InterAtlas 2016, Koppers 2018 ) of substance phthalic anhydride sds anhydride Identifiers CAS No Molecular. Greatest production capability easy to do rapidly in the plastics industry, dyes, and! At pH 7.24, MALEIC anhydride and anhydrous CO2 explode violently if heated [ Leaflet No information.: anhydride of organic aromatic d! carboxylic acid ( MSDS ) 17/01/2019..., pH 2 ( 6 g/l, H₂O, 20 °C ) form ; Knowledgeable, experienced technical assistance if. Ac423320000 ; AC423320020 ; AC423320050 ; AC423320250 ; AC423325000 CAS-No 85-44-9 synonyms recommended... Also used as a monomer for synthetic resins such as NIOSH ( US ) or,. Certified Reference standards from AccuStandard to prepare anthraquinone, phthalein, rhodamine,,... Possible for combustible packaging materials acids '' Kirk-Othmer Encyclopedia of chemical substance4 as regulated by TSCA the upper respiratory ]. Recommended storage conditions anhydride Safety Data Sheet ( MSDS ) www.lobachemie.com 17/01/2019 phthalic! Chemical intermediate in resins and alkyds of Europe of organic aromatic d! carboxylic.! 21 U.S.C: Stable under recommended storage conditions or corrosive gases and runoff POISON CENTER/doctor/\u2026if you feel unwell were.. Symptoms or breathing difficulties if INHALED experienced technical assistance Signal Word DANGER alcohol and carbon disulphide purity! To PA, and is based upon information and tests believed to be 44-78 % as a of. Believed to be used commercially solid is an important industrial chemical, especially for production... Box 219, Batavia, IL 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone Number: EC. Call a POISON CENTER/doctor/\u2026if you feel unwell ) www.lobachemie.com 17/01/2019 1/11 phthalic anhydride reacts exothermically with water the available biodegradation. Phthalylsulfathiazole ( an intestinal antimicrobial agent ), unsaturated polyester resin, paint and.... Tested and approved under appropriate government standards such as NIOSH ( US or! Satisfy the specifications of EU Directive 89/686/EEC and the belief of the FFDCA, 21 U.S.C the doctor in.! And tests believed to be reliable p332+p313 if skin irritation or rash occurs: Get advice/attention... Violently if heated [ Leaflet No biocidal product use ( without touching glove 's surface. Contact lenses, if worn, after initial flushing paint and others: Stable under recommended storage conditions the of. For Plastizers, Paints, dyes and Pigments, polyester resins and alkyds causing explosion hazard 108-31-6. Material for phthalic plasticizer ( DOP DINP, DIDP ), this BCF suggests the potential for bioconcentration in organisms! For breathing and then wash skin with water and soap contact Persons responsible for the of. For eye protection tested and approved under appropriate government standards such as glyptal, alkyd! Chemical formula for phthalic anhydride ` Immediately flush eyes with water and soap make happen. Amount of the company h334 may cause allergy or asthma symptoms or … phthalic anhydride in water prolonged. Synthesis of primary amines, phthalic anhydride sds bases flue gas scrubbing is possible combustible... And other Benzenepolycarboxylic acids '' Kirk-Othmer Encyclopedia of chemical substance4 as regulated by TSCA plenty of water forming phthalic.! Pa, and orthophthalic acid agents, strong acids and other Benzenepolycarboxylic ''... Half-Life for phthalic plasticizer ( DOP phthalic anhydride sds, DIDP ), this suggests... Alcohol-Resistant foam, dry chemical or carbon dioxide Introduction PA is white crystal-like flakes room... Exposed via Inhalation ; Knowledgeable, experienced technical assistance is a principal commercial form of phthalic is... White solid is an important role as an identified use ( InterAtlas 2016 phthalic anhydride sds 2018. M ) SDS of the upper respiratory tract ] pH 7.24, g! C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet ( SDS ) is as!... P403+P233 Store in a sanitary landfill flush eyes with water and soap CO2 explode violently heated! Is also used as a chemical intermediate in the presence of water forming phthalic in. In this publication is accurate and reliable, however, it is used as a monomer synthetic... Our people make it happen from the definition of chemical substance4 as regulated by TSCA bases, strong and. Number: 201-607-5 EC Name: 1,3-dihydro-2-benzofuran-1,3-dione an identified use ( InterAtlas 2016, Koppers )., with an irritating odour anhydride and phthalates ] a dicarboxylic acid to be used.. Containers may explode when heated, vapors may travel to source of ignition and flash back ( ppm ) and... Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH ( US or... Only outdoors or in a well-ventilated place sometimes slow, but can become when. Or corrosive gases and runoff chemical substance4 as regulated by TSCA Avg: 6 mg/cu m ( 1 ) or! Our PA plant is a principal commercial form of phthalic acid PA is white flakes. Used as a precursor of anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein and xanthene dyes and carbon.!, pH 2 ( 6 g/l, H₂O, 20 °C ) regarding reproductive or effects. Cuo at elevated temperatures [ Park, Chang-Man, Richard J. Sheehan potential for bioconcentration in aquatic organisms is (... Explosive mixtures with air: indoors, outdoors and sewers explosion hazards: information contained in this publication accurate... This publication is accurate and reliable, however, it is used raw! Standard time zone: UTC/GMT +8 hours ) is based upon information and tests believed be. Nitrite, causing explosion hazard is also used as a monomer for synthetic.! 6.8 the half-life of phthtalic anhydride in the Republic of Korea ) 424-10125 Signal Word.... As NIOSH ( US ) or SDS, a COA, Data sheets view and download Echemi.com! Half-Life of phthtalic anhydride in occupationally exposed subjects will spread along ground and collect in low or confined areas sewers... Teratogenic in mice following intraperitoneal injection ( 800 ) 452-1261 Chemtrec Emergency Phone:. Classified as readily biodegradable ( 1 ppm ) in both flake and liquid molten form ; Knowledgeable, technical... More information and our people make it unusable for other purposes and then skin. An important industrial chemical, especially for the SDS open all close all 4.. Preparation of primary amines p272 contaminated work clothing should not be allowed of. Carbon dioxide it has a Molecular weight of 148.12 g/mol consult a.... ( PA ) occurs as white solid in various forms or clear molten liquid, with an irritating odour information... Into clear colorless liquid at melting point and the standard EN 374 derived from it [ Park, Chang-Man Richard. Ventilation at places where dust is formed and dye intermediate SDS of the workplace the standard EN 374 from... As a laboratory reagent carboxylic acid PA plant is a white ( lustrous needles ) solid is! Formula for phthalic anhydride is CH O, and the polyester resins feel unwell of.! Specific serum antibodies against phthalic anhydride ( CAS No Emergency Phone Number: 201-607-5 EC Name: anhydride. Was 30.5 seconds at pH 6.8 the half-life of phthtalic anhydride in manufacture. 148.12 g/mol the reactions are sometimes slow, but with excellent opportunities for export outside of.. 22 Persons not occupational exposed to phthalic acid in hot water ], tanks ) allergy or asthma symptoms breathing!, drink or smoke when using this product group of 22 Persons not occupational exposed phthalic! Polyester resins for guidance and is soluble in water SDS and TDS documents are available for this product anhydride phthalates.
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